International Scientific Journals
of Scientific Technical Union of Mechanical Engineering "Industry 4.0"

In view of the practical applications of the piezoelectric ceramics produced from barium titanate (BaTiO3) and barium stannate (BaSnO3), (the BT-BS system), the dielectric behavior of such materials was studied. The starting components (powder of both BaTiO3 and BaSnO3) were synthesizedand structurally characterized in аdvance. Bulk samples of BT-BS (formed as tablets with addition of PVA plasticizer) were prepared using the sol-gel method by varying the BT-BS composition percentage. The samples were characterized by complex electrical impedance spectroscopy and dielectric spectroscopy in the frequency range from 0.1 Hz to 1 MHz. As compared to BaTiO3, an increase with at least 50 % was measured for the value of the room-temperature dielectric constant (e′ – the real part of the dielectric permittivity) of the BT-BS samples containing 15 wt% BaSnO3. In contrast, the 50 wt% content of BaSnO3 led to a decrease of ′ value of BT-BS by a factor of 3.5, due to relatively low e′ value of BaSnO3. Analyses of the frequency spectra of complex electrical impedance and complex dielectric permittivity revealed the dielectric relaxational behavior of the BaTiO3+BaSnO3 system. The results obtained for ′ of BT-BS dielectrics as a function of the temperature were correlated with the data from structural studies. In particular, a specific enhancement of e′ was observed in temperature range around 120C for the BT-BS samples containing 15 wt% BaSnO3. Corresponding conclusions were done. The effects observed show that the synthesized BaTiO3-BaSnO3 ceramics are promising materials for piezoelectric and dielectric applications, e.g., in energy storage devices.

The use of clay as a structural material has been known for centuries. The authors set the task of studying the applicability of clay as a constructive material in the production of beehives. The study aims to make a comparative analysis of temperature conditions in different types and identical in construction beehives by comparing the indicator for ceramic and wooden hives. For the purpose were used three 10-frame hives type “Dadan-Blat” – two ceramic (one made entirely of marl clay, and the other – with increased kaolin content, both ceramic tiles are with high cavity) and one wooden (pine). Measurements of the air temperature and the temperature inside the hives were made for one month. From the obtained results it is established that for the studied beehives, the ceramic hive with high kaolin content has the best thermal insulation properties.

There has been growing interest in the use of the sol-gel approach to form high-quality dielectric materials. Their tailored properties allow for developing functional electronic devices in a scalable and rapid manner. According to physicochemical principles, the displacement and response behavior of charges under an applied external field can manifest in unique dielectric properties, providing useful information to improve the process, design, and quality of electronic devices. Therefore, a systematic and in-depth investigation of the fundamentals of sol-gel dielectrics is necessary. In this Research Update, we present recent advances in various sol-gel-processed dielectric materials and their applications to functional electronic devices. A brief introduction to sol-gel chemistry to form oxide dielectric films and the basis of physical mechanisms under electrical fields are discussed. Along with the dielectric properties, recent achievements of proofof-concept experiments and their various applications to functional electronic devices are introduced. It is expected that further innovations in solution-processed metal oxide dielectrics will achieve cost-effective high-performance functional electronics in the near future.

A system based on BaTiO3 – BaSnO3 (BT-BS) has been developed in search of highly efficient lead-free piezoelectric ceramics. The powder samples were mixed and homogenized in a ratio of 50%: 50% and 15%: 85%. From the compositions thus obtained, tablets with the presence of a PVA plasticizer were formed, which were further annealed in a furnace with a corundum backfill. The temperature regime is in two steps. Drying time up to 800oC with a delay of 1h 30min. and additional heating to 1150°C with one hour delay. The results were characterized by XRD analysis, the relative dielectric constant of the two samples was determined.