INNOVATIVE SOLUTIONS
Vanadium Unveiled: Exploring Jordanian Rock Phosphate and the Crucial Role of Vanadium Technologies in Shaping a Sustainable Energy Future
- 1 Faculty of Engineering, Department of Environmental Engineering, Al-Hussein Bin Talal University, Ma’an, Jordan,
Abstract
Vanadium, a vital element for the advancement of clean energy technologies, holds the potential to revolutionize the energy landscape. This study investigates the distribution of vanadium within Jordan huge rock phosphate deposits, exploring its implications for sustainable energy transitions. Utilizing advanced analytical techniques, including X-ray fluorescence spectroscopy and scanning electron microscopy, were scrutinized the intricate geochemical characteristics of these deposits. The concentrations of Vanadium in different samples of Jordanian rock phosphate, encompassing Al-bied, Al-Hasa, and Eshidiya (A1, A2, A3, S1, and S2), as well as phosphoric acid, were analyzed. The Vanadium concentrations observed were 181 mgkg−1, 204 mgkg−1, 107 mgkg−1, 117 mgkg−1, 55 mgkg−1, 237 mgkg−1, and 291 mgkg−1, and 135 mgkg−1, respectively. The findings unveil promising concentrations of vanadium within Jordanian rock phosphate, positioning the country as a potential key player in the global supply chain of this critical metal. By elucidating the abundance and distribution of vanadium in Jordan rock phosphate, this research not only contributes to the understanding of vanadium fate and distribution but also underscores the imperative of sustainable resource utilization in advancing towards a cleaner and more resilient energy future.
Keywords
References
- Moskalyk, R. R. and Alfantazi, A. M., 2003. Processing of vanadium: a review. Minerals Engineering, 16(9): 793-805.
- Das, B., Prakash, S., Reddy, P.S.R. and Misra, V.N., 2007. An overview of utilization of slag and sludge from steel industries. Resources, Conservation and Recycling, 50(1): 40-57.
- Kuck, P. H. Vanadium. BuMines Mineral Commodity Profile, 1983, 18 pp.
- Vanadium: A Green Metal Critical to Aerospace and Clean Energy, August 1, 2020
- R.RMoskalyka1A.MAlfantazib, Minerals Engineering Volume 16, Issue 9, September 2003, Pages 793-805. Processing of vanadium: a review.
- Amirreza Nasimifar a , Javad Vazifeh Mehrabani, 27 May 2022. A review on the extraction of vanadium pentoxide from primary, secondary, and co-product sources.
- (Guo et al. 1995; Ruck, P. H. 1983; Judd et al. 1984; Okudan et al. 2015 ) Guo W, Fan QM, Hu CP. 1995. Kinetics of vanadium oxidation during bone coal roasting in air. Rare Met. 14 (4):276– 281.
- Judd J. C., Sandberg R. G., Huiatt J. L. Recovery of Vanadium, Uranium, and Phosphate From Idaho Phosphorite Ores UNITED STATES DEPARTMENT OF THE INTERIOR. Donald Paul Hodel, Secretary BUREAU OF MINES Robert C. Horton. Director Ruck, P. H. 1983. Vanadium. BuMines Mineral Commodity Profile, 1983, 18 pp.
- Okudan MD, Akcil A, Tuncuk A, Deveci H (2015) Effect of parameters on vanadium recovery from by-products of the Bayer process, Hydrometallurgy 152:76–8311
- Yang, Z. C.; Zhao, B. Review on the extraction of vanadium from V-bearing solid wastes. Guangzhou Chemical Industry. 2015, 43, 39−40.
- Peng, X. F.; Zhang, Y.; Fan, B. Q.; Zheng, S. L.; Wang, X. J.; Zhang, Y.; Li, P.; Liu, F. Q. 2019.Complexation separation for vanadium and chromium by dithiocarbamate and its application in treatment of chromium-vanadium-bearing slag. Transactions of Nonferrous Metals Society of China. 2019, 29, 2400−2410.
- KHORFAN S., A.WAHOUD and Y. REDA 2001. RECOVERY OF VANADIUM PENTOXIDE FROM SPENT CATALYST USED IN THE MANUFACTURE OF SULPHURIC ACID PERIODICA POLYTECHNICA SER. CHEM. ENG. VOL. 45, NO. 2, PP. 131–137
- Mohammadreza T. 2014. Vanadium : leaching and solvent extraction. PhD. Thesis. The Faculty of Graduate and Postdoctoral Studies (Materials Engineering). THE UNIVERSITY OF BRITISH COLUMBIA, (Vancouver)
- WAKEFIELD, Z. T. (1980), Distribution of Cadmium and Selected Heavy Metal in Phosphate Fertilizer Processing, Publication No. Y-159, Tennessee Valley Authority National Fertilizer Development Center, Muscle Shoals, AL, U.S.A.
- McClellan, G. H. 1980: Mineralogy of Carbonate-flouriteapatites; J. Geol. Soc. London, 137: 675-681.
- Prevot, L. 1994: How to Interpret Trace Element Contents in Phosphorites Using the Geological Data. Rev. Inv. Cient. Ser. Cienc. Mar. U.A.B.C.S. 5(2): 51-61
- BATARSEH1 M., TAYEL EL-HASAN 2009. Toxic Element Levels in the Phosphate Deposits of Central Jordan. Soil & Sediment Contamination, 18:205–215, 2009
- Rorie G., Aleksandar N.N. 2020. The extraction of vanadium from titanomagnetites and other sources. Minerals Engineering Volume 146, 15 January 2020, 106106
- Onipede, A. E. *, Ojo, J. O., Solvent Extraction of Vanadium (V) from Phosphate Solutions with Trioctylmethylammonium Chloride (TOMAC), IOSR Journal of Applied Chemistry (IOSR-JAC) e-ISSN: 2278-5736.Volume 7, Issue 10 Ver. II. (Oct. 2014), PP 34-37
- J. C. Judd, R. G. Sandberg, and J. L Huiatt, Recovery of Vanadium, Uranium, and Phosphate From Idaho Phosphorite Ores
- M. P. Elizalde a , E. García Pavón a , A. Almela a & B. Menoyo 19 May 2008 Vanadium Extraction from Phosphoric Acid Solutions by LIX 860‐ I. Application to Industrial Phosphoric Acid
- United States Patent (19) Gordon J. RossiterStephen F. PeaseCharles B. Snyder. Dec. 15, 1990. Process for the removal of vanadium from wet process phosphoric acid, Dec. 15, 1992
- Khorfan, S., Wahoud, A. Reda, Y. 2001. Recovery of vanadium pentoxide from spent catalyst used in the manufacturing of phosphoric acid. PERIODICA POLYTECHNICA SER. CHEM. ENG. VOL. 45, NO. 2, PP. 131–137.
- Li, M., Fan, G., Li, C.., Deng, Z. and Li. X. 2010. Pressure acid leaching of black shale for extraction of vanadium. Transactions of Nonferrous Metals Society of China, 20(Supplement 1): s112-s117.
- Chen, X., Lan, X., Zhang, Q., Ma, H. and Zhou, J., 2010. Leaching vanadium by high concentration sulfuric acid from stone coal. Transactions of Nonferrous Metals Society of China, 20(Supplement 1): s123-s126.
- Altschuler, Z. S. 1980. The Geochemistry of Trace Elements in Marine Phosphorites, Part I: Characteristic Abundances and Enrichment; SEPM Spec. publ., 29:19-30.
- Wang-xing, L., Zhuo, Z., Zhao-hui, S.U., Xiao-bin, L. and Qing-jie, Z., 2010. Leaching kinetics of calcium vanadate by Na2CO3 solution. Journal of Process Engineering, 10(3): 548-553.