International Scientific Journals
of Scientific Technical Union of Mechanical Engineering "Industry 4.0"

The work is devoted to the development of a solid-phase technology for obtaining high-temperature layered composites from Nballoys. The following are presented: one of the options for the formation of the initial multilayer package and its diffusion welding (1), the microstructure of the obtained composites (2) and the results of testing composites (3) for strength at room temperature and temperatures up to 1350°C, taking into account the structure anisotropy, crack resistance and tests for creep with two options for processing the obtained experimental data.

The crack resistance in fracture mechanics is defined as critical value of stress intensity factor in the plane-strain fracture toughness. A mechanical test is used to assess it under certain conditions. This is a complicated, long and expensive procedure. In practice, it is of interest to determine the crack resistance for construction elements by means non-destructive evaluations (NDE).

In contrast to the melting technologies for the production of high-temperature alloys in the solid-phase technology developed by us, a multi-layer structure of the future composite material is already set at the initial stage of the billet formation. In the work presented, the billets were assembled from Nb- and Mo-foils with one or two-sided coatings of carbon or Si-B. Layered structures of composites were formed during the diffusion welding of packets at 1500°C and a pressure of ~14 MPa. In the place of the coatings, layers of hightemperature carbides or intermetallic Si and B compounds with Nb and Mo formed, which occupied up to ~40% of the cross-sectional area of the composites. The strength and crack resistance at room temperature, strength at a temperature of up to 1500 °C, as well as the modulus of elasticity and density were measured. The presence of intermetallides in the structure of composites leads to a decrease in their density and an increase in the modulus of elasticity.

In this paper we study the structure, phase composition, microhardness, wear resistance boride coatings obtained on metals and alloys at complex saturation with boron and copper in various physical and chemical conditions, namely carrying satiation without application of an external magnetic field (EMF) and in its simultaneous imposition . Studies have shown that the use of EMF when applying boride coatings allows in 1.5 – 2 times reduce the duration of saturation detail and get coatings with high hardness and wear resistance.

Established that the application EMF on carbon steels formed a continuous, homogeneous boride layer, thickness is 2 times higher than the boriding without EMF. On the diffraction patterns of the surface layers of boride coatings obtained after boriding at application EMF fixed presence phases FeB and Fe₂B, the redistribution of the proportion of boride phases, the change of the crystal lattices and the decrease in the volume of the unit lattice phase FeB. When the complex is saturated steel 45 with boron and copper diffusion layer is composed of the phases FeB, Fe₂B and Cu. Chemical heat treatment with the simultaneous action of EMF leads to the formation of phases in the diffusion zone FeB and Cu, crack resistance layers obtained after saturation with boron and copper increases to 2.23 MPa · m^0,5 compared to 1.12 MPa · m^0,5 for boride coatings obtained without action EMF .

Formation diffuse boride layers under the action EMF improves tribological characteristics and leads to an increase in wear resistance of 2.2 – 2.6 times.

Adhesive joints are widely applied in transport engineering. Crack resistance is an important parameter determining the load capacity and durability of adhesive joints. The calculation-experimental method, which allows to raise the accuracy and reliability of an estimation of the crack resistance of the adhesive compositions is proposed. The proposed method can be implemented using a test station that ensures the loading of double cantilever glued beams by equal and oppositely directed moments. The mathematical model for determining the value of crack advancing energy, includes only one independent parameter (the bending moment) was obtained. It is established that change of geometrical parameters of the proposed experimental models slightly effects (less than 3.5 %) on value of crack advancing energy.

Testing method for static crack resistance has been developed and applied for thin sheet (sample thickness ~ 1mm) samples of zirconium alloy Zr-2.5%Nb. Linear parameter of fracture mechanics – stress intensity factor Kc has been determined. Alloy Zr-2.5%Nb after ECAP was tested for corrosion resistance in the physiological Ringer’s solution for two years.

In this paper we study the structure, phase composition, microhardness, crack resistance, wear resistance boride coatings obtained at complex saturation with boron and copper in the application of an external magnetic field (EMF). Investigations have shown that this method allows the application of boride coatings in 1.5 – 2 times decrease the duration saturation detail, and receive coating with high hardness, wear resistance, crack resistance.

It is established that the application EMF formed a continuous, homogeneous boride layer with thickness coatings in 2 times higher than boride coatings without EMF for the equal duration of the process. When imposing EMF in boride layers observed the redistribution quantitative relation boride phases, namely: decrease of volume phase FeB, and on diffractograms surface layers boride coatings obtained after boriding fixed presence phases FeB and Fe₂B. After complex saturation boron and copper in the application of external magnetic fields fixed phases FeB and Cu.

The researches have shown that the highest spalling stress value is reached in boride phases, obtained in powder environments with copper powder at the application of EMF, and respectively is 420 compared with 225 MPa for coating obtained without EMF. Increased shear stress values in complex layers obtained after saturation with boron and copper caused by the formation of phases more viscosity, for which crack K_1c in 1.4 – 2.0 times higher than the initial boride phases FeB and Fe₂B.

Application of EMF at boriding improves tribological characteristics of coatings: decreases coefficient of friction and increase in 1.5 – 2.5 times wear resistance.

Investigated the wear resistance of coatings obtained by saturation with boron and copper under dry friction – sliding on the air, and found that the coatings obtained by saturation with boron and copper have 2 times better wear resistance than the coating after boriding. Found that the saturation of boron and copper complex provides optimal performance when wear boride phases, namely sufficient microhardness – 15.5 MPa, 0,5 0,5 low porosity, increase in viscosity layer, the value K reaches 2.1 MPa · m to compared with 1.2 MPa · m 1C without complex saturation and increasing stress chipping values to 290 MPa compared to 170 MPa for the boride layers.

The results of studies on the application of complex boron coating powder method on hard alloys. Defined phase and chemical composition, thickness and microhardness of the coating on alloys.

It was established that after diffusion saturation of hard alloy in boron mixture for 4 hours formed coating with boride phases TiB, WB, CoB and WC, TiC, whose thickness is 50-60 microns. At complex saturation with boron and copper for 4 hours diffusion saturation formed coating with boride phases TiB, WB, CoB and WC, TiC and separate inclusions of copper with a thickness of the diffusion layer up to 70-80 microns.

Boriding and complex saturation with boron and copper allows in 2 – 2.5 times increase the microhardness of the surface layers of hard alloys, that in turn leads to increased wear resistance.