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Keyword: raman spectroscopy

  • MATERIALS

    Investigation of the properties of Ce dopant titanate ceramics prepared by sol-gel method

    • Lуubеn Lаkov
    • Mihaela Aleksandrova
    • Vladimir Blaskov
    Machines. Technologies. Materials., Vol. 14 (2020), Issue 8, pg(s) 360-361
    • Abstract
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    The research in this article focuses on the synthesis of Ce donated BaTiO3 needed to make a target for magnetron sputtering. Synthesis is BaTiO3 by sol-gel method with a certain concentration of a modifying additive of Ce. The process of the sol-gel method is considered and the obtained results are characterized. Additional termal treatment of the obtained samples was performed at TOC = 900OC in a muffle furnace in Ar / H2 medium and in a laboratory furnace in air. Physicochemical methods by XRD analysis and Raman spectroscopy were used to characterize the results obtained

  • Physical and luminescent properties of glasses in the system WO3-La2O3-B2O3-Nb2O5

    • Iordanova R.
    • Aleksandrov L.
    • Milanova M.
    Science. Business. Society., Vol. 4 (2019), Issue 3, pg(s) 91-94
    • Abstract
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    New multicomponent glasses in the system WO3-La2O3-B2O3-Nb2O5 doped with Eu3+, as a transparent active media for optical application were obtained. Physical parameters as density, molar volume, oxygen molar volume and oxygen packing density were determined. The thermal behavior of the obtained glasses was examined by differential thermal analysis (DTA). It was established that glass crystallization temperature is about 750oC. Microstructural characterization was made by Raman and UV-VIS spectroscopies. Based on the obtained spectral data short-range order and connectivity in glass network were determined. High photoluminescence emissions due to the 4f transitions 5D0→7Fj (j=0-4) of Eu3+ ions were observed. Colorless bulk tungstate glass, containing Nb2O5 with high transparency and high refractive index were prepared.

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