International Scientific Journals
of Scientific Technical Union of Mechanical Engineering "Industry 4.0"

X-ray diffraction analysis of the Fe-35%FKh800-(0.38-2.2%)TiB2 system samples showed that a multiphase composition of materials is formed during the sintering process. The basis of the sintered composite is the ferrite α-Fe phase, which is a metallic ironchromium matrix, with γ-Fe, complex iron-chromium carbide (Fe,Cr)7C3, and carboboride phases in small amounts: borocementite – Fe3(B0.7,C0.3) with a rhombohedral lattice and carboboride Fe23(C,B)6 with a cubic lattice and a number of carbides (Cr7C3, Cr3C2). The research established the non-monotonic nature of the effect of the TiB2 additive content on the lattice parameters of the ferrite α-Fe and austenitic γ-Fe phases, as well as on the change in the intensity of the 111 line of the austenitic phase. According to the phase composition data and studies of the fine structure (substructure) of the sintered samples of the Fe-FKh800-TiB2 system materials, it can be noted that the components of the TiB2 alloying additive take an active part in the formation of the phase composition, as well as in the process of alloying the matrix phase, which is reflected in the numerical values of the substructure parameters.

This work presents a brief overview of the essence, principles and technological features of reactive electrospark processing (RESP), based on a simple, economical and ecological method – electrospark deposition (ESD), which avoids many of the disadvantages inherent in other existing methods. This treatment can optimize the physicochemical properties of the substrate surface and improve the structure, hardness and wear resistance. The application of RESP technology in surface modification of titanium alloys is considered. Research results, including those of the authors of this work, are presented, which demonstrate the possibilities of RESP for reducing
roughness and surface defects and for the synthesis of new phases and ultrafine structures that are not present in the electrode and substrate. The effect of RESP technology on the wear resistance of titanium and titanium alloys is shown. The main dependences of the quality and properties of the treated surfaces on the process parameters are identified, and ways to form reaction phases, to avoid and remove surface defects and to obtain “in-situ” new intermetallic and wear-resistant compounds are presented. The possibilities and prospects for the use of RESP to improve the surface characteristics and properties of titanium and its alloys are indicated.

The article presents the results of investigations of tribotechnical properties of powder composite materials based on the ironhigh-carbon (ФХ800) ferrochrome system during dry friction with ШХ15 steel at various loads of 30, 60, and 100 N. It was found that an increase of the load from 30 to 100 N leads to an increase in the coefficient of friction from 0,45 to 0,5 (for 25% ФХ800) and from 0,40 to 0,46 (for 40% ФХ800). At the same time, the mass wear of samples made of powder materials decreases with an increase in ФХ800 content from 25 to 40 (wt. %) and with growth of the load from 30 to 100 N, respectively, from 3,5 – 8,0 to 0,75 – 1,6 mg/km., which provides wear resistance improvement (km/mm) by 2,8 – 2,2 times. X-ray phase full profile analysis using the Rietveld method established that there are 2 phases: metallic α-Fe (79,68%) and carbide Me7C3 (20,32%) in the composite Fe – 25%ФХ800 and 3 phases: α-Fe (69,5%), γ-Fe (3,96%) and carbide Me7C3 (26,57%) in the Fe – 40% ФХ800 composite. Topographic studies of 2D profiles of worn surfaces of composites after friction under different loads were conducted. The results of optical profilometry show that the main mechanism of destruction of the powder composite surface during dry friction with ШХ15 steel is adhesive wear (seizing) of the contacting surfaces.

This work discusses the properties of 3D titanium alloys with wear-resistant coatings of hard alloy electrodes based on WC-TiB2-B4C and solder mass of Co-Ni-Cr-B-Fe-Si-C, produced by reaction electrospark processing (RESP) at positive and negative polarity. Through profilometric, metallographic, XRD, SEM, EDS and tribological methods, the complex influence of polarity and pulse energy on the topography, composition, properties, and wear characteristics of the coated surfaces was investigated. The differences in the coatings obtained with the two polarities were identified. Coatings with similar roughness and thickness were obtained, which can be changed by changing the modes for RESP within the limits Ra =2.5÷5μm, δ= 8÷40μm, with microhardness 8 to 14 GPa and 2-4 times higher wear resistance than that of the substrate. At RESP with negative polarity and pulse energy up to 0.04 J, the coatings have comparable characteristics and properties to those at positive polarity, but lower roughness, finer structure and lower coefficient of friction. These coatings can be successfully used to reduce roughness and surface defects and improve the wear resistance of 3D titanium alloys. The pulse energy and polarity of RESР, producing coatings with minimum roughness and maximum wear resistance, have been determined.

In this work the possibilities of reducing the roughness and defects of surfaces obtained by 3D printing with selective laser melting (SLM), via reactive electrospark surface modification (ESD) with low-melting AlSi alloys has been shown. The influence of the energy parameters of the ESD process on the roughness, microstructure, microhardness and performance characteristics of the coatings has been studied. Surfaces with new phases and ultrafine crystal-amorphous structure with particle sizes from micro to nano level, with new relief, with thickness up to 15 μm and microhardness up to 11 GPa were obtained, as the initial SLM roughness from Ra = 8-11μm is reduced to Ra=3-5 μm. Possibilities for control of the characteristics of the coatings and purposeful synthesis of new phases by changing the parameters of the spark discharge have been established. The parameters of the ESD process, which provide simultaneous reduction of SLM surface roughness, removal and erasure of the defects and targeted reactive synthesis of new phases with high performance properties and wear resistance, are defined and optimized.

The research of the technology of obtaining new copper-ferrochrome composite material has been done. The results of its structure and properties analysis are presented. The material structure consists of the copper base, non-dissolved coarse inclusions of ferrochrome, diffused zones, forming around these inclusions and phases, having formed in the place of completely dissolved inclusions of ferrochrome fine particles. The material has good mechanical properties and a high wear resistance due to the formed solid solutions of the carbides in the copper.

Analysis of the structural state and phase composition of surface metal layers after combined treatment of steel which includes preliminary surface plastic deformation of the workpiece, electrospark doping with use of rotating disk electrode 2 mm thick, made of WCCo hard alloy and subsequent surface ball smooth rolling, has been performed. It was shown that the use of combined treatment provides a gradient-layered structure with low surface roughness. Phase composition of the obtained layer consist of ferritic α-Fe phase and a number of carbide phases formed during the interaction of the electrode material with steel: F3W3C, WC and W2C semi-carbide. Wear resistance of the material after treatment exceeds similar properties of the original carbon steel up to 4 times.

This study explores the metal of a coating deposited by a high-chromium flux-cored wire alloyed with a BN-TiB2-ZrB2 complex. We investigated the changes in the durometric properties and fine structure of the coating after tempering and subsequent quenching. It is shown that the hardening of the metal of such a coating after quenching consists in the formation of a complex composite structure with an iron-chromium martensitic matrix, a large amount of eutectic and particles of hardening complexes, which leads to an increase in hardness and wear resistance. It has been established that phase transformations in the metal of such a coating are caused by the formation of an eutectic component based on chromium and iron borides, a framework structure and a large number of dispersed titanium nitride particles up to 2.5 μm in size.

Investigations of wear resistance and tensile strength of steel products with diffusional zinc coating obtained in zinc powders with a nanocrystallized surface of powder particles were carried out. The effect of the structural state of the coating on the wear resistance and adhesive grasping with a steel counterbody was established. The prospects of the nanogalvanizing process to improve the strength of steel products are shown.

The development of technologies in modern machine building aims at improving the mechanical and technological properties of the materials. The present study presents an improvement in the mechanical properties of low carbon steels by thermoffusion coatings with nanofibers obtained under different heat treatment regimes. Depending on the type of heat treatment and the size of the zinc particles, different gradient layers can be obtained in depth. This of course reflects positively on the chemical resistance of the material. In addition, it positively affects the mechanical properties of the material by increasing mechanical strength and technological properties by improving the resistance to plastic deformation. With these first studies, there is an impetus for another look to improve the properties of low-carbon steels that are widely applicable in the field of machine building.

In this paper we study the structure, phase composition, microhardness, wear resistance boride coatings obtained on metals and alloys at complex saturation with boron and copper in various physical and chemical conditions, namely carrying satiation without application of an external magnetic field (EMF) and in its simultaneous imposition . Studies have shown that the use of EMF when applying boride coatings allows in 1.5 – 2 times reduce the duration of saturation detail and get coatings with high hardness and wear resistance.

Established that the application EMF on carbon steels formed a continuous, homogeneous boride layer, thickness is 2 times higher than the boriding without EMF. On the diffraction patterns of the surface layers of boride coatings obtained after boriding at application EMF fixed presence phases FeB and Fe₂B, the redistribution of the proportion of boride phases, the change of the crystal lattices and the decrease in the volume of the unit lattice phase FeB. When the complex is saturated steel 45 with boron and copper diffusion layer is composed of the phases FeB, Fe₂B and Cu. Chemical heat treatment with the simultaneous action of EMF leads to the formation of phases in the diffusion zone FeB and Cu, crack resistance layers obtained after saturation with boron and copper increases to 2.23 MPa · m^0,5 compared to 1.12 MPa · m^0,5 for boride coatings obtained without action EMF .

Formation diffuse boride layers under the action EMF improves tribological characteristics and leads to an increase in wear resistance of 2.2 – 2.6 times.

In this paper was investigated the formation of complex diffusion boride layers on metastable austenite Cr-Mn-N steel powder method. Calculate the value of the diffusion coefficient in different physical – chemical conditions and the thermodynamic potential chemical reactions. Defined phase composition layers obtained on the metastable austenite Cr-Mn-N steel. It is established that the application of an external magnetic field (EMF) leads to a redistribution of the proportion boride phases in the surface layers, changes the period of crystal lattice and increasing the diffusion coefficient.

In this paper we study the structure, phase composition, microhardness, crack resistance, wear resistance boride coatings obtained at complex saturation with boron and copper in the application of an external magnetic field (EMF). Investigations have shown that this method allows the application of boride coatings in 1.5 – 2 times decrease the duration saturation detail, and receive coating with high hardness, wear resistance, crack resistance.

It is established that the application EMF formed a continuous, homogeneous boride layer with thickness coatings in 2 times higher than boride coatings without EMF for the equal duration of the process. When imposing EMF in boride layers observed the redistribution quantitative relation boride phases, namely: decrease of volume phase FeB, and on diffractograms surface layers boride coatings obtained after boriding fixed presence phases FeB and Fe₂B. After complex saturation boron and copper in the application of external magnetic fields fixed phases FeB and Cu.

The researches have shown that the highest spalling stress value is reached in boride phases, obtained in powder environments with copper powder at the application of EMF, and respectively is 420 compared with 225 MPa for coating obtained without EMF. Increased shear stress values in complex layers obtained after saturation with boron and copper caused by the formation of phases more viscosity, for which crack K_1c in 1.4 – 2.0 times higher than the initial boride phases FeB and Fe₂B.

Application of EMF at boriding improves tribological characteristics of coatings: decreases coefficient of friction and increase in 1.5 – 2.5 times wear resistance.