The preconditions of forming a structural paradox within the existing technological paradigm, which manifests itself in reducing the parameters of strength and tribological characteristics of composite materials based on polytetrafluoroethylene when administered in their composition of fillers and modifiers of different composition and geometry when the content of 15-20 wt. % Established effects of forming the structural conditions derating improved performance due to the formation of cluster structure of the binder particles (PTFE) and the modifier. The effective technological methods to ensure reducing the likelihood of cluster components in the manufacturing process of highly composites with a filler content of 20-35 wt. %. The technology of producing high-strength wear-resistant fluorine composites, 1.5-20 times superior to common parameters analogues produced under the trademarks "Flubon", "Fluvis", "Superfluvis.". We consider the effective use of highly fluorine composites in mechanical engineering, chemical industry and energy.