Structure and properties of chromium carbide reinforced steel matrix composites produced from powder iron-ferrochrome mixtures

  • 1 Frantsevich Institute for Problems in Materials Science, NAS of Ukrane, Kyiv, Ukraine

Abstract

The influence of high-carbon ferrochrome on the features of structure formation and properties of chromium carbide steels based on the Fe-FKh800 system was investigated. It was shown that the optimal combination of hardness and tensile strength with sufficient crack resistance has a carbide base of 65% Fe – 35% (wt.) FKh800. A typical microstructure of sintered carbide is a metal matrix composite consisting of chromium steel of composition close to Kh17 and double carbide (Cr0.799Fe0,201) 7C3. The effect of TiB2 additive on the structure, phase composition, mechanical and tribotechnical properties of materials based on the Fe- 35 (%,wt.) FKh800 system was also investigated. Additions of titanium borides in the amount of 0.38-1.48 (% wt.) leads to some increase in hardness, noticeable increase in the flexural strength and leads to increase wear resistance of carbidosteels.

Keywords

References

  1. Radomysel'skiy I.D. (1985) Konstruktsionnyye poroshkovyye materialy [Structural powder materials].- K.: Tekhnika,152s.
  2. Tikhonovich V.I., Kovalenko O.I., Loktionov V.A. (1980). Lityye iznosostoykiye materialy, ikh razrabotka i primeneniye [Cast wear-resistant materials, their development and application] – K.: Znaniye,142 s.
  3. Masliuk, V.A., Bondar A.A., Kuras V.B. (2013). Struktura ta vlastyvosti poroshkovykh materialiv kompozytsii zalizo-vysokovuhletsevyj ferokhrom [Structure and properties of powder materials of the composition of iron-high-carbon ferrochrome]. Poroshkovaia metallurhyia – Powder metallurgy, №5/6, 66-74.
  4. Masliuk, V.A., Karaimchuk E.S, Kurochkin V.D. (2018) Struktura, fiziko-mekhanicheskie i tribotekhnicheskie svojstva poroshkovyh materialov zhelezo- vysokouglerodistyj ferrohrom legirovannyh dobavkami Ni3B [Structure, physicomechanical and tribotechnical properties of iron-high-carbon ferrochrome powder materials doped with Ni3B additives]. Poroshkovaia metallurhyia – Powder metallurgy, №3/4, 62-70.
  5. Maslyuk V., Karaimchuk E., Gripachevsky O., Bagliuk G., Sytnyk I. Peculiarities of the interaction of a highly carbonized ferrochrome with iron during sintering of 65% Fe-35% FH800 composite. - Machines. Technologies. Materials.-2019.Vol.13.- Issue8.- p.370-372
  6. Masliuk, V.A., Sytnyk, Ya.A., Pidopryhora, M.I., Yakovenko, R.V. (2015) Vplyv dobavok khromystykh stalej i borydu nikeliu na strukturu ta vlastyvosti poroshkovykh kompozytsijnykh materialiv zalizo – vysokovuhletsevyj ferokhrom FKh800 [Influence of additives of chromium steels and nickel boride on the structure and properties of powder composite materials iron-high carbon black ferrochrome FH800].Poroshkovaia metallurhyia - Powder metallurgy, 5/6, 52-59.
  7. ISO 4498-1-90 “Metal sintered materials, excluding solid alloys. Determination of apparent hardness. Thematerialsare mainly with uniform hardness across the cross-section”.
  8. ISO 3327 "Alloys are solid. Determination of the tensile strength at the transverse bend"
  9. A. Bondar, V. Ivanchenko, A. Kozlov, J.-C. Tedenac. Carbon- Chromium-Iron // Landolt-Börnstein, Numerical Data and Functional Relationships in Science and Technology / ed. by W. Martinsen. – New Series. Group IV: Physical Chemistry. – Ternary Alloy Systems. Phase Diagrams, Crystallographic and Thermodynamic Data Critically Evaluated by MSIT / ed. by G. Effenberg, S. Ilyenko. – Berlin, Heidelberg: Springer-Verlag, 2007. – Vol. 11D2. – P. 1-55.
  10. Rivlin, V.G., “Phase Equilibria in Iron Ternary Alloys.14. Critical Review of Constitution of Carbon-Cromium-Iron and Carbon- Iron-Manganese Systems.”, Int. Met. Rev., 29(4), 299-327 (1984).
  11. Raynor, G.V., Rivlin, V.G., “C-Cr-Fe”, Phase Equilibria in Iron Ternary Alloys, Institute of Metals, London, 143-156 (1988).
  12. Andersson J.-O., “A Thermodynamic Evaluation of the Fe-Cr-C System”, Metall. Mater. Trans. A, 19A, 627-636 (1988).
  13. Hillert, M., Qui, C., “A Thermodynamic Assesment of the C-Cr- Fe-Ni System”, Metall. Trans. A, 22A(10), 2187-2198 (1991).
  14. Hino M., Higuchi K.-I., Nagasaka T., Ban-Ya S., “Thermodynamic estimation on the reduction behavior of iron-chromium ore with carbon”, Metall. Mater. Trans. B, 29B, 351- 360 (1998).
  15. Bungardt, K., Kunze, E., Horn, E., Untersuchungen über den Aufbau des Systems Eisen–Chrom–Kohlenstoff, Arch. Eisenhüttenwesen, 29(3), 193-203 (1958).

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