TECHNOLOGIES
Effects of gamma irradiation processing with two dose rates on the thermal properties of ebony wood
- 1 University of Sofia “St. Kliment Ohridski”, Faculty of Chemistry and Pharmacy, Sofia, Bulgaria
- 2 BULGAMMA, Sopharma AD, Sofia, Bulgaria
Abstract
Gamma radiation treatment for the destruction of biological pests is a widely applied method, due to its high efficiency, penetrating power of gamma rays, the ability to control the absorbed dose, speed and absence of toxic residual products. The application of gamma irradiation processing for preservation and conservation of artefacts made of wood requires knowledge of the possible radiation effects on the structure of its components and the selection of an appropriate absorbed dose and dose rate. Тhe present study is devoted to the side effects of gamma irradiation decontamination on the structure of two ebony woods dated to different radiocarbon ages. The changes induced by gamma irradiation at two dose rates: 0.037 Gy/s and 1 Gy/s with absorbed doses from 5 to 25 kGy using differential scanning calorimetry are presented. The effects of the absorbed dose, the dose rate and the age of the samples on the observed radiation effects are considered. Higher effects on the enthalpy of water loss were registered in the younger ebony wood after irradiation at low dose rate. Slight changes of the temperatures of water loss were found in the younger ebony wood sample. No significant changes in the temperatures of thermal decomposition in both ebony wood samples were measured.
Keywords
References
- Cortella L., Tran K.Q., Gluszewski W.J., Moise I.V., Ponta C.C., Nuclear techniques for preservation of cultural heritage artefacts; IAEA technical cooperation project – RER 8015, Using nuclear techniques for the characterization and preservation of cultural heritage artefacts in European region, 2011, p 44
- Freitag, C.M., Morrell, J.J. Use of γ-radiation to eliminate fungi from wood. For. Prod. J. 48 (3), 1998, 76–78.
- Katušin-Ražem, B., Ražem, D., Braun, M. Irradiation treatment for the protection and conservation of cultural heritage artefacts in Croatia. Radiat. Phys. Chem. 78, 2009, 729–731.
- Despot, R., Hasan, M., Brischke, C., Welzbacher, C.R., Rapp, A.O. Changes in physical, mechanical and chemical properties of wood during sterilisation by γ-radiation. Holzforschung 61, 2007, 267–271.
- Despot, R., Hasan, M., Rapp, A.O., Brischke, C., Humar, M., Welzbacher, C.R., Ražem, D. Changes in selected properties of wood caused by Γ radiation, chapter 14, in: F. Adrovic (Ed.), γ-Radiation, 2012.
- Inyang, S.O., Inyang, I.S., Egbe, N.O. Radiation exposure levels within timber industries in Calabar, Nigeria. J. Med. Phys. 34 (2), 2009, 97–100.
- Rimdusit, S., Wongsongyot, S., Jittarom, S., Suwanmala, P., Tiptipakorn, S. Effects of γ- irradiation with and without compatibilizer on the mechanical properties of polypropylene/wood flour composites. J. Polym. Res. 18, 2011, 801–809.
- Severiano, L.C., Lahr, F.A.R., Bardi, M.A.G., Santos, A.C., Machado, L.D.B. Influence of γ radiation on properties of common Brazilian wood species used in artwork. Prog. Nucl. Energy 52, 2010, 730–734.
- Curling, S., Winandy, J.E. Comparison of the effects of γ- irradiation and steam sterilization on southern pine sapwood. Forest Prod. J. 58 (1), 2008, 87–90.
- Khan, F., Ahmad, S.R., Kronfli, E. γ-radiation induced changes in the physical and chemical properties of lignocellulose. Biomacromolecules 7 (8), 2006, 2303– 2309.
- IAEA, Uses of ionizing radiation for tangible cultural heritage conservation, International Atomic Energy Agency, Vienna, Series: IAEA radiation technology № 6, 2017.
- Baccaro, S, Caccia, B., Onori, S., Pantaloni, M., The influence of dose rate and oxygen on the irradiation induced degradation in ethylene-propylene rubber. Nucl. Insrr. and Meth. in Phys. Res. B 105(1-4), 1995, 97–99.
- Horovatinčić, N., Barešić, J., Bronić, I. K., Obelić, B. Measurement of low 14C activities in a liquid scintillation counter in the Zagreb Radiocarbon Laboratory. Radiocarbon, 46 (1), 2004, 105–116.
- Bronić, I. K., Sironić, A., Barešić, J. Validation of carbonization as a part of benzene synthesis for radiocarbon measurement. Rad. Phys. Chem., 204, 2002, 110721, 1–3.