MATERIALS

Application of thermal-derivative analysis to study phase transformation in AlSi7Mg alloy with different iron content

  • 1 Silesian University of Technology, Poland
  • 2 Superior IndustriesProduction Poland Sp. z o.o., Poland

Abstract

Using an increasing share of aluminum scrap (production and post-production) requires paying special attention to its impurities. Gaseous inclusions (e.g., hydrides) can be removed from the liquid alloy by refining, but the situation is worse with metallic impurities. In Al-Si alloys, one of the worst is iron, which goes into solution due to its low solubility in the solid state, at a content of over 0.4wt.%, it crystallizes in morphologically unfavorable phases, which worsen the functional properties and increase the porosity of aluminum alloys, limiting their use. The crystallization of these phases causes thermal effects that various methods can record. The paper presents studies of phase transformation, especially iron phases, using thermal-derivative analysis occurring in the AlSi7Mg alloy with different iron content. The studies were performed on Crystaldigraph NT3-8K coupled with the MLab program. It was found that the most unfavorable phase is β- Al5FeSi, which crystallizes preeutectic (and mainly primary crystallize) dimensions of up to 1000 μm, causing the formation of shrinkage porosities.

Keywords

References

  1. Brown M.E.: Introduction to thermal analysis techniques and applications, New York, Kluwer Academic Publishers, 2004.
  2. Djurdjevic M.B., I. Vicario, G. Huber: Present and Future Application of the Thermal Analysis in Aluminum Casting Industry, Revista de Metalurgia, 50(1), 2014, 1-12.
  3. Emadi D., L.V. Whiting, S. Nafisi, R. Ghomashchi: Thermal analysis applications in quality control of solidification processes, Journal of Thermal Analysis and Calorimetric, 81(1), 2005, 235–242.
  4. A.J. Ryan: Thermogravimetric Analysis (TGA). Theory and Applications.
  5. Saadatkhan N., A.C. Garcia, S. Ackermann, P. Leclerc, M. Latifi, S. Samih, G.S. Patience, J. Chaouki: Experimental methods in chemical engineering: Thermogravimetric analysis-TGA, The Canadian Journal of Chemical Engineering, 98, 2020, 34-43.
  6. Gol A.O.K.: Quantification of phase transformations using calorimetry and dilatometry, Alberta, University of Alberta, 2015.
  7. Chen G., S. Zhang, Y. Zhu, C. Yang, Q. Shi: Thermo mechanical Analysis of Friction Stir Welding: A Review on Recent Advances, Acta Metallurgica Sinica, 33, 2020, 3-12.
  8. Spink C.H.: Differential Scanning Calorimetry, Methods in Cell Biology, 84, 2008, 115-141.
  9. Menczel J.D., R.B. Prime: Thermal analysis of polymers. Fundamentals and Applications, New Jersy, A John Wiley and Sons, 2009.
  10. Tarasom A.: Thermal analysis: methods, principles, application. Lecture series, 2012.
  11. Gabbott P.: Principles and Applications of Thermal Analysis, Hoboken, Blackwell Publishing Ltd, 2008.
  12. Bouzidi L., M. Boodhoo, K.L. Humphrey, S.S. Narine: Use of first and second derivatives to accurately determine key parameters of DSC thermographs in lipid crystallization studies, Thermochimica Acta, 439(1-2), 2005, 94-102.
  13. Djurdjevic M.B.: Application of thermal analysis in ferrous and nonferrous foundries, Metallurgical and Materials Engineering, 27, 2021, 457-471.
  14. Erbaş K.C.: A new baseline for the Newtonian thermal analysis of casting: two-capacitive system baseline: modeling the effects of the thermal capacity of mold, Journal of Thermal Analysis and Calorimetry, 119(1), 2014,183-189.
  15. Piątkowski J., B. Gajdzik: Testing phase changes in Al-Si alloys with application of thermal analysis and differential calorimetric analysis, Metalurgija, 52, 2013, 469-472.
  16. Zakharchenko E., E. Sirenko, A. Goncharov, A. Bogdan, A. Burbelko, M. Kawalec: New Computer Method of Derivative Thermal Express Analysis of Cast Iron for Operational Prediction of Quality of Melts and Castings, Journal of Casting & Materials Engineering, 3, 2019, 31–42.
  17. -Al5FeSi phase in Al-Si cast alloys, Materials Transaction, 47, 2006, 1303-1312.
  18. Moustafa M.A.: Effect of iron content on the formation of β- Al5FeSi and porosity in Al-Si eutectic alloys, Journal of Materials Processing Technology, 209, 2009, 605-610.
  19. Piątkowski J., S. Roskosz, S. Stach: The Influence of Selected High – Pressure Die Casting Parameters on the Porosity of ENAB-46000Alloy Castings, Advances in Science and Technology 18(5), 2024, 361-371.
  20. Taylor J.A.: The effect of iron in Al-Si cast alloys, ResearchGate, 2004. 1-12.
  21. Taylor, J.A.: Iron-containing intermetallic phases in Al-Si based casting alloys, Procedia Materials Sci., 1, 2012, 19-33.
  22. Ferraro S., A. Fabrizi, G. Timelli: Evolution of sludge particles in secondary die-cast aluminium alloys as function of Fe, Mn and Cr contents, Materials Chemistry and Physics, 153, 2015, 168-179.
  23. Ceschini L., I. Boromei, A. Morri, S. Seifeddine, I. Svensson: Microstructure, tensile and fatigue properties of the Al-10% Si-2% Cu alloy with different Fe and Mn content cast under controlled conditions, Journal of Materials Processing Technology, 209, 2009, 5669-5679.
  24. Piątkowski J., M. Hejne, R. Wieszała: Influence of manganese content on the microstructure and properties of AlSi10MnMg(Fe) alloy for die castings, Archives of Materials Science and Engineering, 123, 2023, 5-12.
  25. Seifedine S., I.L. Svensson: The influence of Fe and Mn content and cooling rate on the microstructure and mechanical properties of A380-die casting alloys, Metallurgical Science and Technology, 27, 2009, 11-20.
  26. Shabestari S.G.: The Effect of iron and manganese on the formation of intermetallic compounds in Al-Si alloys, Materials Science and Engineering A, 383, 2004, 289-298.
  27. Mahta M., M. Emamy, A. Daman, A. Keyvani, J. Campbell: Precipitation of Fe-rich intermetallics in Cr and Co modified A413 alloy, International Journal of Cast Metals Research 18, 2005, 73-79.

Article full text

Download PDF