Table of Contents

  • MACHINES

  • TECHNOLOGIES

  • MATERIALS

    • Luminescent properties of sol-gel synthesized ZrO2 and Sm2O3 coatings on glass

      pg(s) 146-149

      Thin coatings of zirconia oxide (ZrO2) and samarium oxide (Sm2O3) on glass have been prepared by using sol-gel method and dip coating technique. Materials were characterized in detail by X-ray diffraction. The luminescent properties at room temperature were also investigated. Excitation and emission spectra of ZrO2 coating consists of broad bands with maximums at 318 and 365 nm respectively.
      The photoluminescence measurements of samarium coating suggest that can be efficiently excited with 700 nm and consist of emission bands centered at 567, 603, 639 and 707 nm, consistent with characteristic Sm3+ transitions. The CIE (Commission Internationale de L’Eclairage) chromatic coordinates, color purity and color correlated temperature were determined.

    • Ensuring Clean Waterways: The Essential Role of Neutralization in Treating Technological Wastewater

      pg(s) 150-151

      The treatment of technological wastewater through a neutralization process is essential for adjusting the chemical properties of the water. This method aims to ensure that the wastewater meets established discharge limits, thereby protecting aquatic ecosystems and improving water quality in local waterways. Effectively managing process wastewater from large industrial facilities, such as copper rolling mills, presents a significant challenge that requires attention. In this paper, we present experimental testing of the neutralization process for technological wastewater from copper rolling mills, conducted at laboratory levels. Experimental research has shown that the neutralization process involves adding 10% Ca(OH)2 until a pH of 8.5 is achieved. The duration of the neutralization process is 30 minutes. During this time, a flocculant called Settafloc AP-17 is added at a concentration of 0.033%, specifically 6 ml per liter. This method effectively meets the water quality standards outlined in the Regulation on Limit Values of Pollutant Emissions into Water and the deadlines for compliance.

    • Smelting and structure of high-entropy alloys of the FeNiCrCuAl system

      pg(s) 152-156

      This work was aimed to smelt high-entropy alloys (HEAs) based on inexpensive and common metallic elements using iron-based alloys, ligatures, commercially pure metals and study HEAs’ phase structure. High-entropy alloys of the FeNiCrCuAl system were smelted in air using induction furnace in a crucible with a rammed neutral lining made of aluminum and magnesium oxides. Elements of Fe, Ni, Cr, Cu, Al were added by way of high-alloyed cast iron or stainless-steel grade X10CrNiTi18-10 (EN 1.4541), low-carbon ferrochrome of industrial grade FeCr70C1, binary Cu-33Al ligature, tough-pitch copper and semi-finished nickel. The investigated alloys were prepared by lost foam and sand mold casting methods. A study of the microstructure showed the presence of rounded shape branches of dendrites, copper-rich interdendritic space and high-chromium carbides in the structure of samples. The phase composition of the as-cast FeNiCrCuAl alloys was represented by several phases: ordered solid solution with primitive cubic lattice of type B2, solid solutions with BCC and FCC lattices and complex carbides (FeCr)₇C₃.

    • Surface-modified polyethersulfon nanofiltration membranes – preparation, properties and biotechnological prospects

      pg(s) 157-160

      In this study, different methods for surface modification of polyethersulfone nanofiltration membranes are explored in view of improving water-ethanol separation properties. Thin copolymer film deposition as well as surface grafting of hydrophilic monomers is applied and modified membranes are characterized by using Fourier transform infrared spectroscopy, optical microscopy, atom force microscopy, etc. Surface properties of the modified membranes revealed by contact angle measurements together with specific surface area and pore distribution are evaluated and compared to those of the base membrane. The influence of structure and composition of the modifying polymer on overall membrane properties is assessed and discussed in view of their potential biotechnological application.

    • Study on the Failure of Heat Exchanger Tubes in the Chemical Industry

      pg(s) 161-162

      In the chemical industry, heat exchangers play a critical role in maintaining process efficiency. However, these systems are prone to frequent failures, often necessitating extensive maintenance or repairs, which in turn adversely affect the overall economic performance of industrial operations. The chemical industry commonly operates in highly corrosive environments, making corrosion the predominant failure mechanism for heat exchangers. Key factors contributing to corrosion-related failures include defects in fabrication and welding, suboptimal material selection, improper water flow or chemistry management, and the presence of corrosive species in water. This study investigates the corrosion behaviour of heat exchangers under various corrosive conditions, utilizing COMSOL Multiphysics for simulation and analysis.