Kinetic and equilibrium study of the CO2 adsorption on activated carbon
- 1 Wroclaw University of Science and Technology, Poland
The presented research are concerned with the modelling of isotherms and chemical kinetics of mass transport for the CO2 adsorption on activated carbon, taking place in the fluidized and fixed bed. To determine the nature of CO2 binding under low-pressure conditions, adsorption complex and thermodynamic effects occurring during the process, four isothermal models were used: Langmuir, Freundlich, Temkin and Halsey. The evaluation of the factors affecting the course and rate of CO2 binding was based on four kinetic models, i.e. pseudo-first-order (PFO), pseudo-second-order (PSO), intraparticle diffusion (IPD) and the Elovich model. The validation of mathematical models showed that the linearized Freundlich and Halsey isotherms models are best suited to empirical data. In the case of process kinetics, the analysis showed that the non-linearized pseudo-first-order model (PFO) proved to be unrivalled in fitting to experimental data. The comparison of two types of tested beds suggested faster kinetics for a fluidized bed, while a larger amount of CO2 at equilibrium was adsorbed by the fixed bed.
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