TECHNOLOGIES
Optimizing Tensile Testing: The Role of Electrochemical In-Situ Charging in Hydrogen- Metal Interaction Research
- 1 Institute of Metal Science, Equipment and Technologies with Hydroaerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences
- 2 Institute of Metal Science, Equipment and Technologies with Hydroaerodynamics Centre “Acad. A. Balevski” at the Bulgarian Academy of Sciences; Faculty of Chemistry and Pharmacy at Sofia University “St. Kliment Ohridski”, Bulgaria
Abstract
Steel components often operate in hydrogen-rich environments, where hydrogen dissolves in the steel. This leads to a degradation of mechanical properties, shifting the material behavior under load from plastic to brittle. To investigate these changes in mechanical properties of various pure metals and engineering alloys in the presence of hydrogen, it is crucial to maintain a stable hydrogen concentration in the sample throughout the tensile test. This paper presents the possibilities of the in-situ electrochemical charging technique as an alternative. In this method, the test specimen is placed in a specially designed tensile/hydrogenation electrochemical cell filled with electrolyte, where the specimen acts as the cathode during the mechanical tests. In those conditions, hydrogen forms on the surface of the specimen, and some of it diffuses into its internal structure. This method offers a reliable and practical approach for studying hydrogen embrittlement and its impact on material performance.
Keywords
References
- [1!] M. Nagumo, Fundamentals of Hydrogen Embrittlement (Springer Nature, Singapore, 2016).
- [2!] Liu, Q., Yang, S., Shen, L., Zhou, Q., Li, J., Su, Y., Qiao, L., & Yan, Y., 2020. The effect of hydrogen concentration on the fracture surface of medium Mn steels. Engineering Failure Analysis, 108, pp. 104263. https://doi.org/10.1016/j.engfailanal.2019.104263.
- [3!] Meng, B., Gu, C., Zhang, L., Zhou, C., Li, X., Zhao, Y., Zheng, J., Chen, X., & Han, Y., 2017. Hydrogen effects on X80 pipeline steel in high-pressure natural gas/hydrogen mixtures. International Journal of Hydrogen Energy, 42, pp. 7404- 7412. https://doi.org/10.1016/J.IJHYDENE.2016.05.145.
- Dwivedi, S., & Vishwakarma, M., 2018. Hydrogen embrittlement in different materials: A review. International Journal of Hydrogen Energy. https://doi.org/10.1016/J.IJHYDENE.2018.09.201.
- Dadfarnia, M., Nagao, A., Wang, S., Martin, M., Somerday, B., & Sofronis, P., 2015. Recent advances on hydrogen embrittlement of structural materials. International Journal of Fracture, 196, pp. 223-243. https://doi.org/10.1007/s10704-015- 0068-4.
- Nagumo, M., 2016. Fundamentals of Hydrogen Embrittlement. Fundamentals of Hydrogen Embrittlement. https://doi.org/10.1007/978-981-10-0161-1.
- Barrera, O., Barrera, O., Bombač, D., Chen, Y., Daff, T., Galindo-Nava, E., Gong, P., Haley, D., Horton, R., Katzarov, I., Kermode, J., Liverani, C., Stopher, M., & Sweeney, F., 2018. Understanding and mitigating hydrogen embrittlement of steels: a review of experimental, modelling and design progress from atomistic to continuum. Journal of Materials Science, 53, pp. 6251 - 6290. https://doi.org/10.1007/s10853-017-1978-5.
- Li, X., Ma, X., Zhang, J., Akiyama, E., Wang, Y., & Song, X., 2020. Review of Hydrogen Embrittlement in Metals: Hydrogen Diffusion, Hydrogen Characterization, Hydrogen Embrittlement Mechanism and Prevention. Acta Metallurgica Sinica (English Letters), 33, pp. 759-773. https://doi.org/10.1007/s40195-020-01039-7.
- Sun, B., Wang, D., Lu, X., Wan, D., Ponge, D., & Zhang, X., 2021. Current Challenges and Opportunities Toward Understanding Hydrogen Embrittlement Mechanisms in Advanced High-Strength Steels: A Review. Acta Metallurgica Sinica (English Letters), 34, pp. 741 - 754. https://doi.org/10.1007/s40195-021- 01233-1.
- Song, J., & Curtin, W., 2013. Atomic mechanism and prediction of hydrogen embrittlement in iron. . Nature materials, 12 2, pp. 145-51 . https://doi.org/10.1038/nmat3479.
- Djukic, M., Bakić, G., Zeravcić, V., Sedmak, A., & Rajicic, B., 2016. Hydrogen Embrittlement of Industrial Components: Prediction, Prevention, and Models. Corrosion, 72, pp. 943-961. https://doi.org/10.5006/1958.