• TECHNOLOGIES

    Plasma technologies for the synthesis of wear-resistant multifunctional metal matrix composites of the Al–TiC System

    Machines. Technologies. Materials., Vol. 19 (2025), Issue 9, pg(s) 328-331

    A novel two-stage approach for obtaining wear-resistant multifunctional powder composites based on metal powders with highmodulus Ti–TiC system fillers is proposed. The method combines high-voltage electric discharge (HVED) treatment and spark plasma sintering (SPS), offering a promising alternative to conventional techniques for producing Al–Ti–C system composites. This approach enables the development of a unified route for material synthesis using high-energy-density processing. HVED treatment prevents oxidation of metal particles, reduces contamination by tool materials, and initiates the synthesis of additional dispersed strengthening phases. For example, HVED treatment of titanium powder in a hydrocarbon liquid promotes the in situ formation of titanium carbide (TiC) particles.
    The present work investigates the influence of adding Ti–TiC powder—synthesized via HVED in ethanol under reverse polarity mode with a specific energy input of 20 MJ/kg—on the structure, phase composition, and properties of Al–Ti–C metal matrix composites (MMCs). It was shown that the addition of 2 wt% of Ti–TiC powder synthesized via HVED in ethanol to aluminum powder results in an MMC with an electrical resistivity of 0.5 Ω·mm²/m and a hardness of 31 HRB. However, the heat resistance of this composite is 2.5 times lower than that of consolidated pure aluminum powder. Increasing the Ti–TiC content to 10 wt% leads to the formation of a wear-resistant Al–Ti–C composite, whose structure includes Al, Ti, TiC, the intermetallic compound Al₃ Ti, MAX phases Ti₂ AlC and Ti₃ AlC₂ , and free carbon. For the MMC sample with the addition of 10% Ti–TiC, the mass gain per cycle during the heat resistance test is 0.23%/cycle, whereas for samples made from consolidated Al powder it is 0.18%/cycle, indicating that their heat resistance is approximately the same. The wear resistance of this composite is more than three times higher than that of the consolidated base aluminum powder, with wear rates of 0.003 g/km and 0.010 g/km, respectively. This material also demonstrates a hardness of 43 HRB and relatively low electrical resistivity at the level of 0.3 Ω·mm²/m.

  • TECHNOLOGIES

    The influence of the composition of the working fluid on the characteristics of high-voltage electric discharge in the “hydrocarbon liquid–Al powder” disperse system

    Machines. Technologies. Materials., Vol. 17 (2023), Issue 5, pg(s) 180-182

    Physical modeling of processes in a layer of Al powder in kerosene and ethyl alcohol during high-voltage electrical discharges in the spark discharge mode was carried out. The regularities of the distribution of plasma formations in the volume of the discharge chamber were studied when using ethyl alcohol and kerosene as working substances with an increase in the number of discharges. It is shown that the use of kerosene as a working fluid leads to an increase in the intensity of the formation of discharges between particles. It has been established that ethyl alcohol as a working fluid makes it possible to relatively stabilize the discharge mode, as well as to increase the number of discharges before the appearance of visual signs of the presence of residual nanocarbon, as a result of which it is possible to achieve greater dispersion of the processed powders. The possibility of synthesis of submicron and ultradisperse particles during highvoltage electric discharge processing of aluminum powder in a hydrocarbon liquid (alcohol or kerosene) due to the electrothermal effect of the discharge plasma on the powder particles has been confirmed.

  • MATERIALS

    Investigation of the causes of corrosion of galvanized steel pipes used for hot water supply

    Machines. Technologies. Materials., Vol. 15 (2021), Issue 7, pg(s) 283-286

    The object of the study is the part of the galvanized steel pipe (about 1-meter-long) supplied by the customers, which was used to supply hot water inside the residential building and which has corroded during exploitation of 5 years. To clarify the situation, quality of surface coating and microstructure of the obtained galvanized steel pipe was analysed. Electrical stray currents of the pipeline installed in the building were measured. The sample of the hot water was taken and analysed at the certificated laboratory.
    The aim of the investigation was to determine the possible causes of the hot water supply pipe corrosion during sufficiently short time of exploitation.