• TECHNOLOGIES

    The impact of high voltage electric discharge treatment in ethanol on the dispersity and phase composition of Cu – Al powder mixture

    Machines. Technologies. Materials., Vol. 18 (2024), Issue 6, pg(s) 185-188

    Studies of the impact of high voltage electric discharge (HVED) treatment on the dispersion and phase composition of 87,5 % Al + 12,5 % Cu powder system were performed. It was shown that HVED treatment in ethanol with specific treatment energy of 5 MJ/kg leads to the decrease of mean diameter of treated powder from 15 to 11 μm, and the increase of specific treatment energy to 20 MJ/kg leads to the decrease of mean diameter of treated powder from 15 to 6 μm. X-ray diffraction analysis shows that CuAl2 and Al4C3 are synthesized in all considered treatment regimes, and the quantity of these phases depend on the specific treatment energy.
    The use of “three point – plane” electrode system instead of “point – plane” during HVED treatment of 87,5 % Al + 12,5 % Cu powder system in ethanol leads to the increase of quantity of synthesized Al4C3 and CuAl2 phases with the slight decrease in the dispersion efficiency.
    Up to 35% of particles in powder mixture, treated by HVED in ethanol with the use of “three point – plane” electrode system, have diameter close to the diameter of the initial powder mixture.
    It is shown that the preparation of powders with an initial composition of 87.5% Al + 12.5% Cu using HVED treatment in kerosene or ethanol with subsequent consolidation by SPS method allows obtaining metal-matrix composites of the Al – Cu – C system with increased indicators of hardness, electrical conductivity and wear resistance.

  • MATERIALS

    The impact of high voltage electric discharge treatment on the properties of Cu – Al powder mixture

    Machines. Technologies. Materials., Vol. 15 (2021), Issue 6, pg(s) 248-251

    Studies of the impact of high voltage electric discharge (HVED) treatment on the dispersion and phase composition of 87,5 % Al + 12,5 % Cu powder system were performed. It was shown that HVED treatment in kerosene with specific treatment energy of 5 MJ/kg leads to the decrease of mean diameter of treated powder from 15 to 13 μm, and the increase of specific treatment energy leads to the decrease of mean diameter of treated powder from 15 to 6 μm. X-ray diffraction analysis shows that CuAl2 and Al4C3 are synthesized in all considered treatment regimes.
    HVED treatment with increased specific treatment energy leads to the increase of quantity of synthesized Al4C3 phase. The use of “three point – plane” electrode system instead of “point – plane” during HVED treatment of 87,5 % Al + 12,5 % Cu powder system leads to the increase of quantity of synthesized Al4C3 and CuAl2 phases, while the efficiency of powders dispersion slightly decreases. Up to 40% of particles in powder mixture, treated by HVED in kerosene with the use of “three point – plane” electrode system, have diameter close to the diameter of the initial powder mixture

  • The influence of Zn on the corrosion behaviour of amorphous and nanosized rapidly solidified (Al75Cu17Mg8)100-хZnx alloys and their crystalline analogues

    Materials Science. Non-Equilibrium Phase Transformations., Vol. 6 (2020), Issue 3, pg(s) 73-76

    The influence of Zn on the corrosion behavior of amorphous and nanosized rapidly solidified aluminum alloys (Al75Cu17Mg8)100-xZnx (x = 0; 1; 3) at. % and their crystalline analogues was studied. Data were obtained for resistance of basic and rapidly solidified aluminum alloys (Al75Cu17Mg8)100-xZnx (x = 0; 1; 3) at. % to uniform corrosion. It has been found that increasing the percentage of zinc increases the corrosion rate of both base alloys and rapidly solidified ribbons with similar composition. Pitting and intergranular corrosion tests have been performed. The parameters affected area, pitting density and pitting size were evaluated. An XRD analysis of the separated corrosion products was performed. It was found that the chemical composition, and not the amorphous microstructure of the ribbons, was of leading importance for the course of the corrosion process in the studied rapidly solidified ribbons (Al75Cu17Mg8)100-xZnx and base alloys.