TECHNOLOGIES

Effect of production technique on a high silicon al-si-ni sintered alloy structure and properties

  • 1 Institute for Problems in Material Science, Ukraine
  • 2 Institute for Metal Physics, Ukraine

Abstract

An experimental study was carried out to develop a technique for manufacturing a high silicon Al-Si-Ni sintered alloy with a coefficient of thermal expansion close to steels. A stage of hot forging was added to overcome porosity and improve silicon inclusions morphology to obtain better mechanical properties. Liquid and solid phase regimes of sintering were studied for the material made of the elemental components powders mixture as well as of a pre-alloyed powder. The impracticality of liquid-phase sintering modes is shown for this type of material primarily because of the tendency to liquid-phase exudation. It was proposed to carry out a solid-state vacuum sintering with subsequent hot deformation. Only the pre-alloyed powder is suitable for the technique; the other way, it leads to the course and sometimes, not equilibrium intermetallic inclusions will form in place of nickel particles because of the insolubility of Ni in solid Al. It is shown the possibility of successful plastic deformation of this material after sintering despite its extremely low ductility, which helps successfully overcome porosity and improve the characteristics of the microstructure of the material.

Keywords

References

  1. Osintsev O. E. Special features of heat treatment of high-strength rapidly crystallized aluminum alloy 01949 / O. E. Osintsev // Metal Science and Heat Treatment. – 1998. – Vol. 40. – P. 172– 176.
  2. Ahmad Z. Aluminium Alloys: New Trends in Fabrication and Applications / Zaki Ahmad // Intechopen: 2012. – 370 p.
  3. Vasenyev V. V. Development of a composite material based on the Al-Ci-Ni system with a low CTE value and technology for producing rocket and space technology products: Ph.d. tech. science thesis: 05.16.01 / Moscow, 2017. – 149 p. [in Russian]
  4. Rooy E. L. Introduction to Aluminum and Aluminum Alloys / Elwin L. Rooy // 1990 DOI: https://doi.org/10.31399/asm.hb.v02.a0001057
  5. Osinthev O. E. High-strength corrosion-resistant cast aluminum alloys of the Al-Mg system with a high silicon content / O. E. Osinthev, S.L. Nikitin // Moscow.: MATI. – 2008. – 264 p. [in Russian]
  6. Temperature coefficient of linear expansion of steel [Online resource] // Thermalinfo – Access: http://thermalinfo.ru/svojstva-materialov/metally-i-splavy/temperaturnyj-koeffitsient-linejnogo-rasshireniya-stali.
  7. Samsonov, G V. Handbook of the physicochemical properties of the elements. 1968. Web. doi:10.1007/978-1-4684- 6066-7.
  8. Metastable Al–Si–Ni Alloys for Additive Manufacturing: Structural Stability and Energy Release during Heating / [T. Bedo, B. Varga, D. Cristea та ін.]. // Metals. – 2019. – №9. – С. 483 – 501.
  9. Pan X. M. Determination of the isothermal sections of the AlNiSi ternary system at 750 °C and 850 °C / X. M. Pan, Z. P. Jin, J. Zhao. // Metallurgical and Materials Transactions A. – 2005. – Vol. 36. – С. 1757 – 1767.
  10. Construction of the Al–Ni–Si phase diagram over the whole composition and temperature ranges: thermodynamic modeling supported by key experiments and first-principles calculations / [W. Xiong, Y. Du, R. Hu та ін.]. // International Journal of Materials Research. – 2008. – № 6. – С. 598 – 612.
  11. Belov N.A. Phase composition and structure of silumins: Reference book / N.A. Belov, S.V. Savchenko, A.V. Havan // Moscow: MISiS, 2008. – 283 p. [in Russian]
  12. Arribas I. The initial stage of liquid phase sintering for an Al–14Si–2.5Cu–0.5Mg (wt%) P/M alloy / I. Arribas, J. M. Martin, F. Castro. // Materials Science and Engineering A. – 2010. – №527. – С. 3949 – 3966.
  13. Enhancement of liquid phase sintering through Al–Si additions to Al–Cu systems / M. L.Delgado, E. M. Ruiz-Navas, E. Gordo, J. M. Torralba. // Journal of Materials Processing Technology. – 2005. – №15. – С. 280 – 285.
  14. Romanov G. N. Liquid-phase sintering of powder bodies of the Al-Si system / G. N. Romanov. // Russian Journal of Non- Ferrous Metals. – 2011. – №52. – С. 82 – 85.
  15. Su S. S. Development of Hypereutectic Al-Si based P/M Alloys / Su Shei Sia – Birmingham, 2012. – 265 с
  16. Crossin, E. Swelling during liquid phase sintering of Al– Mg–Si–Cu alloys / E. Crossin,, J. Y. Yao, G. B. Schaffer. // Powder Metallurgy. – 2007. – №50. – С. 354 – 358.
  17. Alternative Liquid-Assisted Sintering of Al/Cu Composites Using Selected Powders of As-Cast Al-Zn Alloy / E. L.Ortiz, W. R. Osório, A. D. Bortolozo, G. S. Padilha. // Metals. – 2022. – №12. – С. 962 – 977.
  18. Kaverinsky V. V. About Al–Si Alloys Structure Features and Ductility and Strength Increasing After Deformation Heat Processing / V. V. Kaverinsky, Z. P. Sukhenko, G. A. Bagluk, D. G. Verbylo / Metallofiz. Noveishie Tekhnol. – Vol. 44, No. 6. – 2022. –P. 769–784. doi: 10.15407/mfint.44.06.0769

Article full text

Download PDF