International Scientific Journals
of Scientific Technical Union of Mechanical Engineering "Industry 4.0"

The electrochemical corrosion properties in a 3% NaCl solution of the titanium-based multicomponent composite of the 65TiH2–30FeSiMn–B4C system were investigated. The kinetics and the mechanism of anode dissolution of metals and oxidation of specimens have been studied by using polarization curves, chemical and x-ray phase analyses. It was found a decrease in the titanium carbide peaks on the X-Ray defractions also the titanium silicon carbide almost disappears after immersing the sample in a 3% NaCl solution. Formation of silicon and boride phases of titanium in the synthesis process leads to an increase in corrosion resistance due to the inhibition of the velocities of both the anode and cathode processes.

The influence of high-carbon ferrochrome on the features of structure formation and properties of chromium carbide steels based on the Fe-FKh800 system was investigated. It was shown that the optimal combination of hardness and tensile strength with sufficient crack resistance has a carbide base of 65% Fe – 35% (wt.) FKh800. A typical microstructure of sintered carbide is a metal matrix composite consisting of chromium steel of composition close to Kh17 and double carbide (Cr0.799Fe0,201) 7C3. The effect of TiB2 additive on the structure, phase composition, mechanical and tribotechnical properties of materials based on the Fe- 35 (%,wt.) FKh800 system was also investigated. Additions of titanium borides in the amount of 0.38-1.48 (% wt.) leads to some increase in hardness, noticeable increase in the flexural strength and leads to increase wear resistance of carbidosteels.

The effect of TiB2 additives on the sintering temperature, structure, and mechanical properties of materials based on the Fe-FeCr800 system is investigated. It was shown that the introduction of titanium diboride additives leads to the activation of compaction and to a 50–70ºС decrease in the sintering temperature of the pressed composites based on iron. It has been studied that the addition of titanium diboride in the range of 0.38-0.74 (% wt.) provides, with a slight increase in hardness, an increase of 20-25% of the flexural strength of the composite 65Fe-35 FeCr800800 (% wt.), and also provides the formation of a multiphase, microheterogeneous structure of the matrix-filled composite type, which consists of chromium steel of the X6Cr17 type, double iron-chromium carbides M7C3, M3C and complex carboborides of the Me3(CB) type.

This publication traces the peculiarities of metal powder production for powder metallurgy. Of the variety of methods, particular attention is paid to those that are most widely used in practice – reduction and powdering methods. Metallurgical photo of iron powders obtained by different technological processes are presented, as well as tables with the basic technological properties of iron powders obtained by reduction and powdering.

For simulation of processes of compaction or forging of products from powder materials, a method of permeable elements is proposed. The essence of the method is to use elements whose shape is regulated in advance, and, unlike the finite element method, where the elements coincide with the material volumes and their masses are unchanged, here the masses elements are variable, and material can flow between adjacent cells. Examples of using the method for modeling the processes of forging of porous preforms in closed and open dies, as well as in a closed die with a compensation cavity, are presented.

The influence of temperature of sintering on structure formation, phase composition, microhardness of components of powder composite 65 % wt. Fe – 35 % wt. FH800 were investigated. It has been established that the increase in the temperature of sintering from 1050 ºС to 1250 ºС leads to some increase in volumetric shrinkage, density and decrease in porosity of samples of material which was made from coarse-grained source powders of industrial production components. It was found that the sintering of green compacts in the range of 1000-1300 ºС causes significant changes in the chemical and phase composition of the carbide component of the composite, which are described by a series of phase transformations: M7C3 → M3C (1000-1150 ºС) → M7C3 (1200 ºС) → M3C (1250-1300 ºС)