International Scientific Journals
of Scientific Technical Union of Mechanical Engineering "Industry 4.0"

Barium titanate ceramics doped with samarium were synthesized by low temperature sol-gel method. The physicochemical characterization of the samples was carried out by X-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). A pure BaTiO3 cubic phase was obtained. A technological regulation has been developed for the preparation of test samples .Monitoring ofthe relative dielectric permittivity of Sm-doped BaTiO3 ceramics with temperature changes (at frequency of 10 kHz) was realized.The resulting curve is typical of ferromagnetic material. The synthesized barium titanate ceramics possesses a high dielectric constant – 17500 at a Curie temperature Tc (65oC). The obtained values for the relative dielectric permittivity and Curie temperature of Sm-doped barium titanate ceramics are much better in comparison to conventionally non-doped BaTiO3-εr = 2000 and Tc = 120°C.

In summary form, some trends in the production and application of foamed silicate materials obtained from recycled waste materials are presented. The existing possibilities for the use of different fractions of foam glass granules for the preparation of various products (lightweight concrete, colored decorative panels, etc.) are considered. Experimental samples are prepared in which the average value of the thermal conductivity coefficient =0.24±0.13 W/m. K was established. The main technological factors determining the operational characteristics of the material and the existing potential prospects for their optimization are analyzed.

A conceptual design of a technological line for the production on the one hand of a continuous flat strip and block and on the other hand granules and pieces of foam glass, including a ware house for raw materials, a workshop for preparation of materials, workshops for foamed granules and a continuous flat strip of foam glass, workshop for composite elements semi O, P and slabs, repair section and warehouse for finished products is presented The necessary equipment and materials, building the technological line and functioning of the plant as a whole, are presented.

The sol-gel process is a well-known and reliable process for obtaining materials and coatings of different structure and properties. An important feature of this method is the choice of starting precursors to obtain the desired compositions. The complexity of the technology is due to the difficult process control. For this purpose it is necessary to accurately calculate the stoichiometry to obtain the final phase. Thus, the sol-gel technology is widely used as in the production of coatings by immersion and spraying, aerogels and others. However, there are many other applications such as electronic materials that have not yet been well studied. In this study, after a brief explanation of the process, some of the most important applications are considered.

Experimental ceramic samples were obtained in which the presence of CaMgSi2O6 (predominant phase), MgCr2O4, CaAl2Si2O8 and quartz was detected by X-ray diffraction analysis. During the microscopic examination of the prepared sections, two mineral phases were established: main – clinopyroxene and secondary – green spinel. The presence of prismatic-granular and skeletal structure was found. In the formed dominant diopside phase the presence of numerous inclusions of magnesium-chromium spinel with green color (sizes up to 0,05 mm) was observed evenly distributed in the sections determining the characteristic green color of the samples.

In this paper we present the results of atomic force microscopy (AFM) characterization of the surface morphology of the nanostructured titanium oxide films featuring with Sm2O3 by the sol-gel method in order to increase the corrosion resistance of stainless steel. Two types of titanium precursors were applied – titanium (IV) isopropoxide Ti[OCH(CH3)2]4 and titanium(IV) butoxide Ti(OCH2CH2CH2CH3)4.

Different corrosion-resistant coatings based on various SiO2, TiO2, ZrO2 and CeO2oxides have been applied to various steels by the sol-gel method and spray pyrolysis. The obtained experimental coatings were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and weight loss measurements in 3.5% NaCl medium. TiO2 / SiO2 and CeO2/SiO2 coatings treated at lower temperatures (500oC) have been shown to exhibit higher corrosion resistance than ZrO2/SiO2 samples. Increasing the treatment temperature decreases the protective properties of the invesitgated coatings. The enhanced protective properties of TiO2/SiO2 are probably due to their low crystallized fine grained structure and relatively dense surface without visible cracks.

Sol gel TiO2-ZrO2 composite films were dip coated on stainless steel substrates and treated at 300, 400 and 500oC. The morphology and surface features were examined by Scanning electron microscopy (SEM) and X ray photoelectron spectroscopy (XPS). Xray diffraction analyses (XRD) was applied to investigate the phase composition. The corrosion resistances of the coatings were studied by evaluation of the weight loss in NaCl medium. According to XRD while the Zr-Ti composites are amorphous after treatment even at 500oC. The surfaces of the coatings possess typical island structure. The coatings, treated at 500oC ehxibit higher corrosion resistance than the other two type of samples. This could be explained by the amorphous structure of the composites, which lowers ion and electron conduction, high hydrophobicity and lower oxygen content.