Innovations
Vol. 9 (2021), Issue 4, pg(s) 158-163

INNOVATIVE SOLUTIONS

The practical applications of the concept of energy and technological compliance in materials science of polymer nanocomposites

  • 1 Molder Ltd – Grodno, Belarus

Abstract

The analysis of the mechanisms of implementation of the concept of multilevel modification in materials science and technolog y of polymer nanocomposites is carried out. It has been shown that the mechanisms of structure formation at the molecular, supramolecular and interfacial levels in nanocomposite materials based on industrial polymers of the class of polyamides, polyolefins, fluoropla stics modified by components that implement the nanostate phenomenon are based on:
– the formation of adsorption physical bonds in the boundary surface due to the energy interaction of active centers of nanosized particles with various shapes and components of the surface layer, which change the parameters of the rheological, stress-strain and adhesive characteristics of the composites;
– the demonstration of a structuring action by nanosized particles and components of the surface layer of particles, which mani fests itself in the form of supramolecular and interphase ordering, physical compatibilization and non-chain stabilization, which increase the thermodynamic compatibility of the components of polymer-polymer and polymer-oligomer blends and inhibit thermo-oxidative and destructive processes in composites, causing a non-additive increase of the parameters of their stress-strain, adhesive and tribological characteristics.

Keywords

References

  1. Hussain C.M. Handbook of Nanomaterials for Industrial Application. Imprint: Elsevier, 2018. – 1130 p.
  2. Eklund P.C., Roa A.M. Fellerene polymers and fullerene polymer composites. Berlin: Springer Science & Business Media, 2013. – 395 p.
  3. Silva M., Alves N.M. Graphene-polymer nanocomposites for biomedical applications. Polymers for Advanced Technologies. 2018. Iss. 29. Vol. 2. – P. 687–700.
  4. Grady B.P. Recent developments concerning the dispersion of carbon nanotubes in polymer. Macromolecular Rapid Communications. 2010. Iss. 31. Vol. 3. – P. 247–257.
  5. Avdeychik S.V., Struk V.A., Antonov A.S., Goldade V.A. Metodologiia vybora komponentov dlia funktsional'nykh nanokompozitov na osnove termoplastov [Component selection methodology for functional thermoplastic nanocomposites]. Petrochemistry–2020: Proceedings III International Scientific and Technical Forum on Chemical Technologies and Oil and Gas Processing, December 2–3, 2020, Minsk. – P. 83–87. (in Russian).
  6. Avdeychik S.V. Metodologicheskie printsipy sozdaniia nanokompozitsionnykh materialov na osnove promyshlennykh termoplastov [Methodological principles of creating nanocomposite materials based on industrial thermoplastics]. Petrochemistry–2020: Proceedings III International Scientific and Technical Forum on Chemical Technologies and Oil and Gas Processing, December 2–3, 2020, Minsk. – P. 79–82. (in Russian).
  7. Avdeychik S.V. Metodologicheskie printsipy realizatsii fenomena nanosostoianiia v materialovedenii i tekhnologii kompozitov i metallopolimernykh sistem [Methodological principles of the implementation of the nanostate phenomenon in materials science and technology of composites and metal-polymer systems]. Vysshaia shkola: nauchnye issledovaniia: Proceedings of the Interuniversity International Congress, May 27, 2021, Moscow. – P. 73–100. (in Russian).
  8. Avdeychik S.V., Liopo V.A., Struk V.A. K mekhanizmu deistviia dopingovykh nanorazmernykh modifikatorov v polimernykh matritsakh [To the mechanism of action of doping nanoscale modifiers in polymer matrices]. Plasticheskie massy. 2007. Vol. 8. – P. 36–41. (in Russian).
  9. Liopo V, Avdeychik S., Ryskulov A., Struk V. Natural layer silicate as a modifier for polymeric nanocomposites. Engineering structures and technologies. 2010. Vol. 2. – P. 5–11.
  10. Avdeychik S.V., Struk V.A., Voropaev V.V. Tekhnologicheskie printsipy formirovaniia vysokoprochnykh iznosostoikikh ftorkompozitov [Technological principles for the formation of high-strength wear-resistant fluorine composites]. Plasticheskie massy. 2013. Vol. 12. – P. 3–8. (in Russian).
  11. Avdeychik S.V., Kostyukovich G.A., Krav-chenko V.I., Lovshenko F.G., Lovshenko G.F., Panteleenko F.I., Rogachev A.V., Struk V.A., Tochitskiy E.I. Nanokompozitsionnye mashino-stroitel'nye materialy: opyt razrabotki i primeneniia [Nanocomposite construction materials: development and application experience]. Grodno, GrSU, 2006. – 403 p. (in Russian).
  12. Struk V.A., Prushak V.Ya., Avdeychik S.V., Liopo V.A., Dmitrochenko V.V., Protasenya A.V. Polimer-silikatnye mashinostroitel'nye materialy: fiziko-khimiia, tekhnologiia, primenenie [Polymer-silicate construction materials: physical chemistry, technology, application]. Minsk, Tekhnalogiya, 2007. – 431 p. (in Russian).
  13. Avdeychik S.V., Liopo V.A., Ryskulov A.A., Struk V.A. Vvedenie v fiziku nanokompozitsionnykh mashinostroitel'nykh materialov [Introduction to the physics of nanocomposite construction materials]. Grodno, GGAU, 2009. – 439 p. (in Russian).
  14. Avdeychik S.V., Struk V.A., Antonov A.S. Faktor nanosostoianiia v materialovedenii polimernykh nanokompozitov [The nanostate factor in the material science of polymer nanocomposites]. Saarbrücken, LAP LAMBERT Acad. Publ., 2017. – 468 p. (in Russian).

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